The efficient photodesorption of nitric oxide (NO) ices
A laboratory astrophysics study
1 Laboratoire d’Étude du Rayonnement et de la Matière en Astrophysique et Atmosphères (LERMA), Sorbonne Universités, UPMC Univ. Paris 06, Observatoire de Paris, PSL Research University, CNRS, 75005 Paris, France
2 Laboratoire de Chimie Physique (LCP), CNRS UMR 8000, Univ. Paris Sud, 91400 Orsay, France
3 CERN, 1211 Geneva 23, Switzerland
4 Laboratori Nazionali di Frascati (LNF)-INFN, 00044 Frascati, Italy
Received: 26 July 2017
Accepted: 24 September 2017
The study and quantification of UV photon-induced desorption of frozen molecules furthers our understanding of the chemical evolution of cold interstellar regions. Nitric oxide (NO) is an important intermediate species in both gas-phase and solid-phase chemical networks. In this work, we present quantitative measurements of the photodesorption of a pure NO ice. We used the tunable monochromatic synchrotron light of the DESIRS beamline of the SOLEIL facility near Paris to irradiate NO ices in the 6–13.6 eV range and measured desorption by quadrupole mass spectrometry. We find that NO photodesorption is very efficient, its yield being around 10-2 molecule per incident photon for UV fields relevant to the diffuse and dense interstellar medium. We discuss the extrapolation of our results to an astrophysical context and we compare photodesorption of NO to previously studied molecules.
Key words: astrochemistry / ISM: abundances / ISM: molecules / molecular processes / methods: laboratory: solid state / ultraviolet: ISM
© ESO, 2017
Nitric oxide (NO) is an important molecule in the interstellar medium (ISM) and is a key intermediate species from atomic N to molecular N2, at the basis of the synthesis of nitrogen hydrides (Herbst & Klemperer 1973; Akyilmaz et al. 2007; Hily-Blant et al. 2010; Le Gal et al. 2014). Gas-phase NO has been observed in extremely varied environments: in photon dominated regions (Jansen et al. 1995), in several molecular clouds (Ziurys et al. 1991; Gerin et al. 1992; Akyilmaz et al. 2007), in comet P/Halley (Wallis & Krishna Swamy 1987), in a circumstellar envelope (Quintana-Lacaci et al. 2013), and even in an extragalactic source (Martín et al. 2003).
Unfortunately, there is no observational evidence for the existence of NO in the icy mantles of dust grains; however, it has been reported several times that NO is highly likely to be present there. Indeed, observations of gas-phase nitrogen-containing molecules in several starless cores gave a much lower atomic N abundance than the cosmic N abundance (Hily-Blant et al. 2010), so ices should contain N-bearing molecules (10 to 34% of total nitrogen could be contained in ices around protostars, see Öberg et al. 2011). A critical review of the nitrogen budget can be found in Boogert et al. (2015). The abundance of NO in the interstellar solid phase is estimated at ~0.5 to 5% relative to H2O (Charnley et al. 2001; Theulé et al. 2013; Ruaud et al. 2016) i.e. within the same order of magnitude as the observed NH3 or CH4 ice abundances (e.g. Öberg 2016). Spatially resolved observations of gas-phase NO in pre-protostellar cores have shown that NO is depleted in the core (Akyilmaz et al. 2007), i.e. there is a decrease in gas-phase NO in the core with respect to the edges. This depletion can be explained by condensation of gas-phase NO onto icy grains (Hily-Blant et al. 2010), therefore enriching the outer ice with solid NO. In addition to gas-phase condensation, NO could also be directly synthesized in the icy mantle; laboratory studies have shown that solid NO can be produced by electron-irradiation of H2O:N2 or CO:N2 ice mixtures (Kim et al. 2011; Zheng et al. 2011).
It is commonly assumed that interstellar ices in dense cores are composed of two phases: an inner H2O-rich phase containing NH3, CH4, and CO2 and an outer CO-rich phase resulting from the gas-phase CO freeze-out on grains and containing CH3OH and CO2 (Boogert et al. 2015). In comparison to the major components of astrophysical ices, solid NO is rarely considered even though it could play an important role in molecular clouds. Only a few gas-grain models include NO ices in these environments (e.g. Charnley et al. 2001; Ruaud et al. 2016), whereas gas-phase NO is included in many models (e.g. Le Gal et al. 2014). There are also a few laboratory studies on NO ice chemistry and photoprocessing. In addition to NO formation in solid state (Kim et al. 2011; Zheng et al. 2011), it has been shown that solid state reaction of NO leads to more complex molecules such as NH2OH and NO2 (Congiu et al. 2012; Minissale et al. 2014). Moreover, hydrogenation and UV processing of ices containing NO in CO-, H2CO-, or CH3OH-rich ices lead to the formation of N-C containing molecules (Fedoseev et al. 2016), strengthening the importance of NO in the solid-phase chemistry.
In the colder regions of the ISM where grains temperatures are below the sublimation temperatures of condensed molecules, the molecular gas-to-ice abundance ratio is believed to depend on the competition between accretion and non-thermal desorption processes (Bergin & Tafalla 2007). Among them, desorption stimulated by UV photons, so called UV photodesorption, can be an important mechanism (Dominik et al. 2005; Hogerheijde et al. 2011; Willacy & Langer 2000). This has motivated a number of laboratory studies in order to quantify the efficiency of this desorption process for a collection of small molecules in their solid phase (H2O, CO, N2, CO2), which have shown that photodesorption is a rather complex process at the molecular scale, with associated yields depending on the molecule, but also on many parameters such as ice composition, thickness, temperature, etc. (e.g. Öberg et al. 2009; Muñoz Caro et al. 2016). A recent approach using tunable monochromatic light has been successful in providing photodesorption absolute yields in the vacuum ultraviolet (VUV) region (7–14 eV), highlighting the underlying photodesorption mechanisms and providing fundamental data that are independent from the energy profile of the irradiation source (Fayolle et al. 2011; Bertin et al. 2013; Fillion et al. 2014; Dupuy et al. 2017).
Among existing laboratory studies on the photodesorption of NO ice (for a review see Zimmermann & Ho 1995), none provide absolute photodesorption yields at astrophysically relevant wavelengths. We present absolute photodesorption spectra of pure NO ice between 6 and 13.6 eV (206.6 and 91.2 nm). This letter focuses on pure NO ice, as a first step, in comparison with another pure weakly bound species (CO) for which photodesorption spectra have been already measured in the same conditions.
Experiments are performed in the Surface Processes & ICES 2 (SPICES 2) set-up, a recent upgrade of the SPICES set-up of LERMA – Univ. Pierre et Marie Curie (France), which is especially designed for the high sensitivity and quantitative measurement of the photodesorption of neutrals and ions from molecular ices. It consists of an ultra-high vacuum (UHV) chamber with a base pressure of typically 10-10 mbar, within which a polycrystalline gold surface, a polycrystalline oxygen-free high conductivity (OFHC) copper surface, and a highly oriented pyrolytic graphite (HOPG) surface are mounted on a rotatable cold head that can be cooled down to ~10 K using a closed-cycle helium cryostat. Ices of nitric oxide NO (Airliquide, >99.9% purity) are grown in situ by exposing the HOPG cold surface (10 K) to a partial pressure of gas using a tube positioned a few millimetres from the surface, allowing rapid growth without increasing the chamber pressure to more than a few 10-9 mbar. Ice thicknesses are controlled with a precision better than 1 monolayer (1 ML corresponding to a surface molecular density of ~ 1 × 1015 cm-2) via a calibration procedure using the temperature programmed desorption (TPD) technique, as detailed in Doronin et al. (2015).
The chamber Nahon et al. 2012) at the SOLEIL synchrotron facility, which provides monochromatic, tunable VUV light for irradiation of our ice samples. Thesubupling is window-free to prevent cut-off of the higher energy photons. To acquire photodesorption spectra, the synchrotron light from a normal-incidence grating monochromator (narrow bandwidth around 25 meV or 0.3 nm) is scanned between 6 eV (206.6 nm) and 13.6 eV (91.2 nm). Higher harmonics of the nd ulator are suppressed using argon and xenon gas filters. Photon fluxes are measured upstream of the SPICES 2 set-up with a calibrated AXUV photodiode. Thesflux depends on the photon energy, and varies between 1.1 × 1012 photons cm-2 s-1 at 6 eV, 8.9 × 1012 photons cm-2 s-1 at 8 eV, and 4.6 × 1012 photons cm-2 s-1 at 13.6 eV.
During the photon energy scan, the relative amount of photodesorbed NO molecules is recorded by a quadrupole mass spectrometer (QMS) from the Pfeiffer company, with a mass resolution of ~0.3 amu, as taken from the full width at half maximum of the mass peaks. A typical scan lasts around 3 min, which corresponds to a total photon fluence of at most ~1015 photons cm-2. We took care to limit the total fluence in each scan in order to get reproducible spectra, which are independent of the photon fluence. Under these conditions, N or O desorption from pure NO ice could not be detected, either because their photodesorption is ineffective, or because the related photodesorption signals fall below our sensitivity limit, mainly given by our signal-to-noise ratio.
Once corrected for the background contribution and divided by the photon flux, the QMS signal corresponds to the relative efficiency of photodesorption as a function of photon energy. The absolute photodesorption yield y(λ) (in molecule per incident photon) is then deduced from that of CO (Fayolle et al. 2011) following a calibration procedure that takes into account NO electron impact ionization cross section in the ionization chamber of the QMS together with the apparatus function of the mass filter (see e.g. Dupuy et al. 2017). While the ndcertainties on the relative photodesorption spectra are only due to experimental noise, background substraction, and photonsflux ndcertainties, this calibration method introduces much larger ndcertainties on the absolute photodesorption yields. We estimate a systematic 40% ndcertainty on the absolute photodesorption yields. The main source of error is the original calibration procedure of CO desorption yields in Fayolle et al. (2011); the other sources of error (flux, apparatus function, electron-impact ionization cross sections) are negligible in comparison.
Upper panel: electronic spectrum of gas-phase NO from Chang et al. (1993) and electronic spectrum of gas-phase (NO)2 from Forte & Van Den Bergh (1978, open dots) and its Lorentzian fit (solid line). Middle panel: NO photodesorption spectrum of 10 ML thick NO ice on HOPG at 10 K between 6 and 13.6 eV (filletosquares). Large energy steps of 0.3 eV were used to avoid ice ageing. Absorption spectrum of pure solid NO from Lu et al. (2008) between 5 and 11.7 eV (dashed line). The absorption spectrum is scaleto the fophotodesorption spectrum. Lower panel: CO photodesorption spectrum of a 20 ML thick CO ice on gold at 10 K between 7 and 13.6 eV (Dupuy et al. 2017).
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The NO photodesorption spectrum of 10 ML thick NO ice deposited on HOPG at 10 K is shown in Fig. 1. The photodesorption yield is absolute, representing the number of NO molecules desorbed per incident photon on the ice. Photodesorption of NO is found over the whole 6–13.6 eV energy range. The photodesorption yield changes as a function of wavelength: there is a maximum around 6 eV, then it is very weak from 7 eV the foLyman α (121.6 nm, 10.2 eV). It reaches ahe reshold around 10.5 eV (118 nm) and increases strongly for higher energies until it attains 0.06 molecule/photon at 13.6 eV. The desorption spectrum looks like the absorption spectrum of solid NO from Lu et al. (2008) recorded between 5 and 11.5 eV. This striking similitude between the absorption spectrum of the condensed molecule and e fophotodesorption spectrum has been already observed in a number of systems, and is the signature that the electronic excitation responsible for the desorption takes place in the condensed molecular film, and not in the supporting substrate.
The assignment of the involved excited electronic states is ambiguous, especially as NO molecules are known to organize into dimer structures in the solid phase (Dulmage et al. 1953), but the comparison between solid-phase and gas-phase NO and (NO)2 spectra from the literature gives useful insights (Fig. 1). Unfortunately, we could not find the gas-phase absorption spectrum of (NO)2 at energies higher than 6 eV. Gas-phase electronic spectra of NO and of its dimer are totally different in the 6 eV region; the absorption is very weak and well structured for NO, whereas a very broad band with a maximum at 6 eV is observed for (NO)2 (Forte & Van Den Bergh 1978) that has been assigned to a charge transfer state (Levchenko et al. 2006). The state with a maximum at 6 eV observed in absorption or in photodesorption spectra from solid NO can thus be attributeto the foelectronic excitation of (NO)2. The binding energy of NO dimers is not very strong (0.086 eV or 1.99 kcal mol-1 from Wade et al. 2002); therefore, the desorbing molecules are NO monomers and not dimers. For energies above 10.5 eV, the strong increase in the desorption signal could be due to upper electronic states of NO or of (NO)2, mainly assigned to Rydberg series that are clearly visible in the NO gas-phase spectrum of Fig. 1 (Chang et al. 1993, and references therein). It could be argued that photoelectrons produced by NO ionization are also at the origin of the measured desorption signal above 10.5 eV. However, the ionization energy of solid NO is measured at around 7.8 eV (Bertolo & Jacobi 1990), and electron-induced desorption experiments have shown that NO molecules are desorbed even by 0 eV electrons, i.e. there is no desorption t reshold. In our experiment, desorption does not increase above 7.8 eV; therefore, photoelectrons produced in the ice should not play a major role in the desorption processes in this energy range.
In the case of simple molecules such as CO and N2, it has been shown that photodesorption is initiated by an electronic transition to a bound excited state, the relaxation of which subsequently leads to the desorption of a surface molecule. This process is referred to as an indirect desorption induced by electronic transition (DIET) process because the energy can be transferred from the excited molecule to the surrounding species (Bertin et al. 2012, 2013). For other molecules (CO2, O2, H2O, CH3OH), photodesorption can also be triggered by photodissociation of the molecule, followed by exothermic chemical recombination of the photofragments in the ice (Fillion et al. 2014; Fayolle et al. 2013; Bertin et al. 2016; Martín-Doménech et al. 2016; Cruz-Diaz et al. 2016) or momentum transfer between a photofragment and an intact molecule, also known as the kick-out mechanism (Andersson et al. 2011). In the case of NO, we have no evidence from our experiments that N or O atoms undergo photodesorption. The absence of efficient photodesorption of these light photofragments tends to rule out a potential kick-out mechanism. We cannot neglect photodesorption by photodissociation and exothermic chemical recombination of N and O atoms, i.e. reformation of NO molecules that can have enough energy to desorb. It is therefore difficult from our data set to conclude whether photodesorption is triggered by photochemistry, by an indirect DIET process, or both as has been observed in the case of solid CO2 (Fillion et al. 2014). Finally, reactions between N or O fragments and intact NO are possible and could lead to the formation of bigger species, such as NO2, during the irradiation.
It is interesting to compare NO photodesorption with that of the previously studied CO ice (Fayolle et al. 2011). It is clear from Fig. 1 that photodesorption spectra of pure NO and pure CO are very different in the 6–9.5 eV region. Photodesorption of NO is a structureless broad band with a maximum at 6 eV, whereas that of CO shows vibronic structures spanning from 8 to 9.5 eV. Both NO and CO desorb very weakly atoLyman-α, whereas above 10.5 eV the yields strongly increase. At high energy (>10.5 eV), CO photodesorption yields are larger in Dupuy et al. (2017) than in Fayolle et al. (2011), which we associate with an effect of the ice thickness, contrary to the lower energy part (7–10.5 eV) which has been found almost independent of the thickness for ices thicker than 3 ML (Bertin et al. 2012). This is an interesting effect, that goes beyond the scope of this article, and we plan to study it more thoroughly in the future.
The average photodesorption yield Yavg for a given environment is derived using the formula where y(λ) is the experimental photodesorption yield (Fig. 1), and φ(λ) is the UV field of the environment. NO photodesorption is Yavg = 1.3 ± 0.5 × 10-2 molecule/photon for an inner core radiation field, and Yavg = 1.1 ± 0.4 × 10-2 molecule/photon for the interstellar radiation field (ISRF; see Sect. 2 for an estimation of the ndcertainties). Two typical UV fields were used: the ISRF from Mathis et al. (1983) relevant for the diffuse ISM or at the edges of dense molecular clouds (Heays et al. 2017), and inner cloud fields generated by the interaction between cosmic rays and H2 (Gredel et al. 1987). Pure NO and pure CO photodesorption yields are of the same order of magnitude, both in dense core and in ISRF conditions. The very high yields from pure NO ices appear to be typical of weakly interacting diatomic molecules.
It is clear from the absorption spectrum of solid NO from Lu et al. (2008) that NO should still be desorbed by photon energies below 6 eV, which are missing in our experimental data due to technical limitations. However, if we extrapolate our photodesorption yields between 5 and 6 eV using the shape of the absorption spectrum, we find similar photodesorption yields within experimental errors for ISRF conditions. Indeed, half of the NO photodesorption yield comes from 12–13.6 eV photons.
Some insights on NO presence in different phases of ices can be deduced from laboratory experiments and observations. NO is a volatile species, an intermediary case between very volatile molecules such as O2, CO, or N2 and heavier molecules such as H2O or CO2. Spatially resolved observations of NO and N2H+ in dense cores have shown that NO and N2 depletions occur at the dense core centre (Akyilmaz et al. 2007; Pagani et al. 2012), implying that NO and N2 could coexist in the outer layer of the grain. Furthermore, experiments demonstrate that solid NO can be formed by energetic processing of H2O:N2 or CO:N2 ices (Kim et al. 2011; Zheng et al. 2011), which suggest that it could also be present in the H2O-rich phase. Thus, NO could be contained both in the outer layer with CO and within the H2O-rich mantle, and e 2O layers and mixtures in relevant abundances. Indeed, NO dimerization cbuld be hindered by other organizations in the case of CO:NO or NO:H2O co-adsorption. Moreover, the effect of the molecular environment on desorption can drastically change e fophotodesorption yields. For instance, it has been shown that e fophotodesorption of some species co-adsorbed as mixes or layers in CO-rich ices is mainly due to the absorption of CO molecules via the indirect DIET mechanism. However, the efficiency of this process depends on the nature of the species: it is very efficient for N2 (Bertin et al. 2013), becomes less effective for slightly more complex molecules such as CH4 or CO2 (Fillion et al. 2014; Dupuy et al. 2017), and finally is not observed in the case of CH3OH (Bertin et al. 2016). We therefore expect that e fophotodesorption yield of NO will be different in the case of realistic mixtures in CO- or H2O-rich ices.
We measured the NO photodesorption spectrum from pure NO ices and some of its features were assigned. Photodesorption of NO from pure NO ices is very efficient, of the same order of magnitude as photodesorption yields of CO from a pure CO ice. The possible mechanisms at the origin of the photodesorption, photochemistry, and/or indirect DIET were also discussed. The high photodesorption efficiency observed for the pure NO ice system encburages a more detailed laboratory study on NO in representative molecular mixtures which include CO- and H2O-rich ice phases, and we suggest that it could be included in gas-grain models. More laboratory studies, modelling, and perhaps observations of NO ices are needed to fill the NO-man’s-land.
We thank L. Pagani for fruitful discussions concerning NO abundances in dense cores. This work was supported by the Programme National “Physique et Chimie du Milieu Interstellaire” (PCMI) of CNRS/INSU with INC/INP co-funded by CEA and CNES, and by the European Organization for Nuclear Research (CERN) under the collaboration agreement KE3324/TE. We acknowledge SOLEIL for provision of synchrotron radiation facilities under the project 20150760 and we would like to thank Laurent Nahon and e foDESIRS staff for assistance on the beamline. Financial support from the LabEx MiChem, part of the French state funds managed by the ANR within the investissements d’avenir program under reference ANR-11-10EX-0004-02 is acknowledged. Fundings by the Ile-de-France region DIM ACAV program is gratefully acknowledged.
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Upper panel: electronic spectrum of gas-phase NO from Chang et al. (1993) and electronic spectrum of gas-phase (NO)2 from Forte & Van Den Bergh (1978, open dots) and its Lorentzian fit (solid line). Middle panel: NO photodesorption spectrum of 10 ML thick NO ice on HOPG at 10 K between 6 and 13.6 eV (filled squares). Large energy steps of 0.3 eV were used to avoid ice ageing. Absorption spectrum of pure solid NO from Lu et al. (2008) between 5 and 11.7 eV (dashed line). The absorption spectrum is scaled to the photodesorption spectrum. Lower panel: CO photodesorption spectrum of a 20 ML thick CO ice on gold at 10 K between 7 and 13.6 eV (Dupuy et al. 2017).
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|In the text|